Research progress in solid phase microextraction (SPME) in tea aroma analysis
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摘要: 茶叶香气是影响茶叶品质的重要因子之一,其组成复杂且在茶叶中的含量低。固相微萃取作为目前茶叶香气的富集手段,具有操作简便快速等优点,是茶叶香气研究的热点。本文综述了近年来茶叶香气特征和固相微萃取(SPME)技术及其在茶叶香气分析中的应用。Abstract: Tea aroma was an important index of tea quality, and the content of aroma in tea was relatively low and its composition was complex. Solid phase microextractoin was a simple and rapid tea aroma compounds extraction method and it was one of research hotspots of tea aroma. In this paper, these tea aroma characteristics combined with recent applications of solid phase microextractoin technology in tea aroma research were reviewed.
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Keywords:
- tea /
- aroma compounds /
- solid phase microextractoin /
- GC/MS
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[1] ARTHUR CL, PAWLISZYN J.Solid phase microextraction with thermal desorption using fused silica optical fibers[J].Anal Chem, 1990, 62 (19) :2145-2148.
[2] 王俊平, 姚玉超, 王硕.分子印迹材料萃取与高效液相色谱联用技术[J].食品研究与开发, 2011, 32 (2) :171-175. [3] 冯国琳, 王焕英, 邢广恩.新型萃取技术研究进展[J].化工中间体, 2013 (2) :1-5. [4] 刘晓博, 庞晓莉, 孔维婷, 等.信阳毛尖特征赋香成分的研究[J].食品工业科技, 2013, 34 (1) :108-112. [5] 司辉清, 沈强, 庞晓莉.新型花茶的香气特征研究[J].茶叶科学, 2010, 30 (3) :167-172. [6] 周珊, 赵立文, 马腾蛟, 等.固相微萃取 (SPME) 技术与质谱技术联用研究进展[J].现代科学仪器, 2006, 16 (3) :14-20. [7] 张来, 余正文, 杨占南, 等.SPME-GC-MS分析瀑布毛峰茶叶的赋香成分[J].光谱实验室, 2012, 29 (2) :672-676. [8] 詹家芬, 陆舍铭, 孟昭宇, 等.固相微萃取/加速溶剂萃取-气相色谱-质谱法分析青山绿水茶叶的挥发性成分[J].色谱, 2008, 26 (3) :301-305. [9] 欧阳石光.茶叶香气指纹图谱及特征识别的初步研究[D].泰安:山东农业大学, 2011. [10] 姚姗姗.茶叶香气化学研究[D].杭州:浙江大学, 2005. [11] 王力, 林智, 吕海鹏, 等.茶叶香气影响因子的研究进展[J].食品科学, 2010, 31 (15) :293-298. [12] 袁海波, 尹军锋, 叶国柱, 等.茶叶香型及特征物质研究进展[J].中国茶叶, 2009, 31 (8) :14-15. [13] 窦宏亮, 李春美, 顾海峰, 等.采用HS-SPME/GC-MS/GCOlfactometry/RI对绿茶和绿茶鲜汁饮料香气的比较分析[J].茶叶科学, 2007, 27 (1) :51-60. [14] LIN J, ZHANG P, PAN ZQ, et al.Discrimination of oolong tea (Camellia sinensis) varieties based on feature extraction and selection from aromatic profiles analysed by HS-SPME/GC-MS[J].Food Chemistry, 2013, 141 (1) :259-265.
[15] 代毅, 须海荣.采用SPME-GC/MS联用技术对龙井茶香气成分的测定分析[J].茶叶, 2008, 34 (2) :85-88. [16] 兰欣, 汪东风, 张莉, 等.HS-SPME法结合GC-MS分析崂山绿茶的香气成分[J].食品与机械, 2012, 28 (5) :96-101. [17] 王家明, 王彩娇, 王超, 等.CTC顶空固相微萃取-气质联用法分析霍山黄芽茶叶的香气成分[J].中国实验方剂学杂志, 2012, 18 (18) :85-87. [18] 赵珗, 肖成杰, 蔡宝国, 等.气相色谱-质谱法中4种不同捕集方式对茶叶香气成分测定的影响[J].食品科学, 2011, 32 (16) :283-289. [19] WU F, LU WP, CHEN JH, et al.Single-walled carbon nanotubes coated fibers for solid-phase microextraction and gas chroma-tography-mass spectrometric determination of pesticides in tea samples[J].Talanta, 2010, 82 (3) :1038-1043.
[20] 梁永津.新型固相微萃取涂层的制备和表征[D].广州:中山大学, 2010. [21] 杨江帆, 杨广, 梁小虾, 等.茉莉花茶香气的SPME/GC-MS检测方法[J].热带作物学报, 2009, 30 (11) :1698-1704. [22] 刘晓慧, 张丽霞, 王日为, 等.顶空固相微萃取-气相色谱-质谱联用法分析黄茶香气成分[J].食品科学, 2010, 31 (16) :239-243. [23] 申东, 沈强, 潘科, 等.基于HS-SPME/GC-MS定性半定量分析藤茶特征香气[J].贵州农业科学, 2010, 38 (11) :67-70. [24] 蒋生祥, 冯娟娟.固相微萃取研究进展[J].色谱, 2012, 30 (3) :219-221. [25] MARTIN-ESTEBAN A.Molecularly-imprinted polymers as a versatile, highly selective tool in sample preparation[J].TrAC Trends in Analytical Chemistry, 2013, 45:169-181.
[26] MULLETT WM, MARTIN P, PAWLISZYN J.In-tube moleculary imprinted polymer solid-phase microextraction for the selective determination of propranolol[J].Anal Chem, 2001, 73 (11) :2383-2389.
[27] 杨红丽, 王镨, 王翊如, 等.两种新型固相微萃取纤维的研制和表征[J].浙江大学学报:工学版, 2008, 42 (7) :1276-1280. [28] 刘学, 刘飞, 黄先智, 等.桑叶绿茶香气成分的SPME-GCMS分析[J].食品科学, 2012, 33 (20) :238-242. [29] 孔维婷, 刘建军, 司辉清.固相微萃取与气相色谱-质谱联用分析信阳毛尖香气成分[J].食品科学, 2012, 33 (12) :185-189. [30] 王力, 蔡良绥, 林智, 等.顶空固相微萃取-气质联用法分析白茶的香气成分[J].茶叶科学, 2010, 30 (2) :115-123. [31] WANG LF, LEE JY, CHUNG JO, et al.Discrimination of teas with different degrees of fermentation by SPME-GC analysis of the characteristic volatile flavour compounds[J].Food Chemistry, 2008, 109 (1) :196-206.
[32] 王道平, 甘秀梅, 梁致远, 等.固相微萃取法与同时蒸馏萃取法提取茶叶香气成分[J].西南农业学报, 2013, 26 (1) :131-135. [33] 王峰, 曹福亮, 张洪娟.SPME法与SDE法测定雨花茶香气成分比较[J].林业科技开发, 2010, 24 (3) :123-125. [34] 苗爱清, 吕海鹏, 孙世利, 等.乌龙茶香气的HS-SPMEGC-MS/GC-O研究[J].茶叶科学, 2010, 30 (增刊1) :583-587. [35] LIN J, DAI Y, GUO YN, et al.Volatile profile analysis and quality prediction of Longjing tea (Camellia sinensis) by HSSPME/GC-MS[J].J Zhejiang Univ Sci B, 2012, 13 (12) :972-980.
[36] 陈美丽, 唐德松, 张颖彬, 等.GC-MS结合化学计量学对茶叶品质的判别研究[J].浙江大学学报:农业与生命科学版, 2013, 39 (1) :84-91. [37] 郭丽, 蔡良绥, 林智, 等.基于主成分分析法的白茶香气质量评价模型构建[J].热带作物学报, 2010, 31 (9) :1606-1610. [38] PONGSUWAN W, FUKUSAKI E, BAMBA T, et al.Prediction of Japanese Green Tea Ranking by Gas Chromatography/Mass Spectrometry-Based Hydrophilic Metabolite Fingerprinting[J].J Agric Food Chem, 2007, 55 (2) :231-236.
[39] YE NS, ZHANG LQ, GU XX.Discrimination of Green Teas from Different Geographical Origins by Using HS-SPME/GC-MS and Pattern Recognition Methods[J].Food Analytical Methods, 2012, 5 (4) :856-860.
[40] 陈金美, 曾景斌, 陈文峰, 等.新型固相微萃取涂层的研究进展[J].化学进展, 2009, 21 (9) :1922-1929.
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